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Nevertheless, the kinetic data for our mutants and rate constants for ScGrx7 and PfGrx between 10 5 10 6 M 1 s 1 are too slow for a diffusion-controlled reaction and point towards important short-lived enzymesubstrate interactions and rate-limiting re-orientations of the substrate at the enzyme surface

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B12 deficiency can distort HbA1c results, but the direction is variable results may be spuriously low or high depending on the degree of anaemia, red cell changes, and the assay used